By David H. Volman, George S. Hammond, Klaus Gollnick
Ultrafast Photochemical Intramolecular cost move and Excited country Solvation (P. Barbara & W. Jarzeba). Atmospheric Reactions related to Hydrocarbons: FTIR reports (H. Niki & P. Maker). Excited kingdom Reactivity and Molecular Topology Relationships in Chromophorically Substituted Anthracenes (H.-D. Becker). Photophysics and Photochemistry of Phytochrome (K. Schaffner et al.). Photochemical Mechanism in unmarried Crystals: FTIR experiences of Diacyl Peroxides (M. Hollingsworth & J. McBride). Index. Cumulative Index, Volumes 1-15. learn more... content material: ADVANCES IN PHOTOCHEMISTRY; CONTENTS; Ultrafast Photochemical Intramolecular cost move and Excited country Solvation; Atmospheric Reactions regarding Hydrocarbons: FTIR reviews; Excited kingdom Reactivity and Molecular Topology Relationships in Chromophorically Substituted Anthracenes; Photophysics and Photochemistry of Phytochrome; Photochemical Mechanism in unmarried Crystals: FTIR reviews of Diacyl Peroxides; Index; Cumulative Index, Volumes 1-15. summary: Ultrafast Photochemical Intramolecular cost move and Excited country Solvation (P. Barbara & W. Jarzeba). Atmospheric Reactions concerning Hydrocarbons: FTIR experiences (H. Niki & P. Maker). Excited country Reactivity and Molecular Topology Relationships in Chromophorically Substituted Anthracenes (H.-D. Becker). Photophysics and Photochemistry of Phytochrome (K. Schaffner et al.). Photochemical Mechanism in unmarried Crystals: FTIR stories of Diacyl Peroxides (M. Hollingsworth & J. McBride). Index. Cumulative Index, Volumes 1-15
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This material is an excellent dye. It also has electrochromic properties, as discussed later in this book, and it can be changed reversibly between deep blue and transparent states by ion intercalation/deintercalation. Tungsten trioxide plays a special role in electrochromism. The stoichiometric material is yellowish to greenish in bulk form. It can be chemically reduced to produce a blue compound, and Berzelius (373-4, 374) reported as early as in 1815 that the color change took place when hydrogen was passed over gently warmed tungsten trioxide.
3135- 6). Molecular Bonding 39 method. 6 nm was found in laser evaporated W oxide films (3208). Electron diffraction measurements were used to derive RDFs in work by Ramans et al. (2831) and Kukuyev et al. (1952). Data from the former of these studies are included in Fig. 5(b), where they are represented by the dashed curve. One can note a good qualitative agreement with the X-ray data. The RDF was influenced by exposure of the film to water vapor (1952). EXAFS for the Lnt edge of tungsten was applied to evaporated W oxide films in some recent work using high-intensity synchrotron radiation (244, 246, 380, 528, 1987, 3433).
I 2 - 0 - --2 Evaporated "4 W oxide -- bulk W , 0 Fig. ---.. 1 , 600 Resistivity of W oxide films evaporated onto substrates at different temperatures. An arrow marks the resistivity of bulk W (at 600~ After Miyake et al. (2340). Density 31 (3073, 3687), 10 nm/s (1889), and 15 nm/s (1972-4, 1981). For thin films made by evaporation one can increase the deposition rate, at the expense of having a smaller surface evenly coated, simply by placing the substrate closer to the vapor source. Detailed evaporation conditions are seldom given; exceptions are in works by Goulding and Thomas (1271), Demiryont and Nietering (877), and Rousselot et al.
Advances in Photochemistry by David H. Volman, George S. Hammond, Klaus Gollnick